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The commercial vehicle industry continues to move in the direction of improving brake thermal efficiency while meeting more stringent diesel engine emission requirements. This study focused on demonstrating future emissions by using an exhaust burner upstream of a conventional aftertreatment system. This work highlights system results over the low load cycle (LLC) and many other pertinent cycles (Beverage Cycle, and Stay Hot Cycle, New York Bus Cycle). These efforts complement previous works showing system performance over the Heavy-Duty FTP and World Harmonized Transient Cycle (WHTC). The exhaust burner is used to raise and maintain the Selective Catalytic Reduction (SCR) catalyst at its optimal temperature over these cycles for efficient NOX reduction. This work showed that tailpipe NOX is significantly improved over these cycles with the exhaust burner.

A series of 500-hour duration tests were conducted using two medium-speed diesel engines to screen residual blended fuels for future locomotive field testing. The test fuels were railroad diesel fuel and two No. 6 fuel oil/diesel fuel blends. The performance, wear, fuel handling, and deposit characteristics of each fuel were evaluated. Combustion deposits, fuel handling, and wear were found to be the primary factors that limited No. 6 fuel oil content of blends. A 40 SSU viscosity blend was found to be acceptable for field trials, but a 55 SSU blend was not due to fuel filtration and combustion deposits problems.

Engine and aftertreatment solutions have been identified to meet the upcoming ultra-low NOX regulations on heavy duty vehicles in the United States and Europe. These standards will require changes to current conventional aftertreatment systems for dealing with low exhaust temperature scenarios while increasing the useful life of the engine and aftertreatment system. Previous studies have shown feasibility of meeting the US EPA and California Air Resource Board (CARB) requirements. This work includes a 15L diesel engine equipped with cylinder deactivation (CDA) and an aftertreatment system that was fully DAAAC aged to 800,000 miles. The aftertreatment system includes an e-heater (electric heater), light-off Selective Catalytic Reduction (LO-SCR) followed by a primary aftertreatment system containing a DPF and SCR.

A series of tests using an open beam laser ignition system in an engine run on pre-mixed, gaseous fuels were performed. The ignition system for the engine was a 1064 nm Nd:YAG laser. A single cylinder research engine was run on pre-mixed iso-butane and propane to determine the lean limit of the engine using laser ignition. In addition, the effect of varying the energy density of the ignition kernel was investigated by changing the focal volume and by varying laser energy. The results indicate that for a fixed focal volume, there is a threshold beyond which increasing the energy density [kJ/m3] yields little or no benefit. In contrast, increasing the energy density by reducing the focal volume size decreases lean performance once the focal volume is reduced past a certain point. The effect of ignition location relative to different surfaces in the engine was also investigated. The results show a slight bias in favor of igniting closer to a surface with low thermal conductivity.

Ideally, complete thermal decomposition of urea should produce only two products in active Selective Catalytic Reduction (SCR) systems: ammonia and carbon dioxide. In reality, urea thermal decomposition reaction includes the formation of isocyanic acid as an intermediate product. Being highly reactive, isocyanic acid can initiate the formation of larger molecular weight compounds such as cyanuric acid, biuret, melamine, ammeline, ammelide, and dicyandimide [1,2,3,4]. These compounds can be responsible for the formation of deposits on the walls of the decomposition reactor in urea SCR systems. Composition of these deposits varies with temperature exposure, and under certain conditions, can create oligomers such as melam, melem, and melon [5, 6] that are difficult to remove from exhaust systems. Deposits can affect the efficiency of the urea decomposition, and if large enough, can inhibit the exhaust flow.

Ideally, complete decomposition of urea should produce only two products in active Selective Catalytic Reduction (SCR) systems: ammonia and carbon dioxide. In reality, urea decomposition reaction is a two-step process that includes the formation of ammonia and isocyanic acid as intermediate products via thermolysis. Being highly reactive, isocyanic acid can initiate the formation of larger molecular weight compounds such as cyanuric acid (CYN), biuret (BIU), melamine (MEL), ammeline (AML), ammelide (AMD), and dicyandimide (DICY). These compounds can be responsible for the formation of deposits on the walls of the decomposition reactor in urea SCR systems. Composition of these deposits varies with temperature exposure, and under certain conditions can create oligomers that are difficult to remove from exhaust pipes. Deposits can affect efficiency of the urea decomposition, and if large enough, can inhibit the exhaust flow and negatively impact ammonia distribution on the SCR catalyst.

A new diesel engine system adopting alternative combustion with rich and near rich combustion, and an airflow-dominant control system for precise combustion control was used with a 4-way catalyst system with LNT (lean NOx trap) to achieve Tier II Bin 5 on a 2.2L TDI diesel engine. The study included catalyst temperature control, NOx regeneration, desulfation, and PM oxidation with and without post injection. Using a mass-produced lean burn gasoline LNT with 60,000 mile equivalent aging, compliance to Tier II Bin 5 emissions was confirmed for the US06 and FTP75 test cycles with low NVH, minor fuel penalty and smooth transient operation.

Mitigation of urea deposit formation and improved ammonia production at low exhaust temperatures continues to be one of the most significant challenges for current generation selective catalytic reduction (SCR) aftertreatment systems. Various technologies have been devised to alleviate these issues including: use of alternative reductant sources, and thermal treatment of the urea-water solution (UWS) pre-injection. The objective of this work was to expand the knowledge base of a potential third option, which entails chemical modification of UWS by addition of a titanium-based urea/isocyanic acid (HNCO) decomposition catalysts and/or surfactant to the fluid. Physical solid mixtures of urea with varying concentrations of ammonium titanyl oxalate (ATO), oxalic acid, and titanium dioxide (TiO2) were generated, and the differences in NH3 and CO2 produced upon thermal decomposition were quantified.

Piston ring and liner wear measurements and analyses were performed in a production 3.6L V6 gasoline engine with radiolabelled engine parts. Three isotopes were generated: one in the engine liner using surface layer activation; one each in the top ring face and top ring side using bulk activation. Real-time wear measurements and subsequent rates of these three surfaces were captured using the radioactive decay of the isotopes into the engine oiling system. In addition, surface roughness and wear profile measurements were carried out using white light interferometry. The results from Phase I provided insights on evolution of wear and wear rates in critical engine components in a gasoline engine. Phase II will extend this work further and focus on evaluating the fuel additive effects on engine wear.

Exhaust gas recirculation (EGR) has long been used in gasoline and light-duty diesel engines as a NOx reduction tool. Recently imposed emission regulations led several heavy-duty diesel engine manufacturers to adopt EGR as part of their strategy to reduce NOx. The effectiveness of this technology has been widely documented, with NOx reduction in the range of 40 to 50 percent having been recorded. An inevitable consequence of this strategy is an increase in particulate emission, especially if EGR was used in high engine load modes. Selective catalytic reduction (SCR), a method for NOx reduction, is widely used in stationary applications. There is growing interest and activity to apply it to mobile fleets equipped with heavy-duty diesel engines. Results of this work indicate that SCR has the potential to dramatically reduce NOx in diesel exhaust. Reductions greater than 70 percent were reported by several including the Institute's previous work (SAE Paper No. 1999-01-3564).

Particulate matter (PM) and NOX are two major pollutants generated by diesel engines. Modern diesel aftertreatment systems include selective catalytic reduction (SCR) technology that helps reduce tailpipe NOX emissions when coupled with diesel exhaust fluid (DEF/urea) injection. However, this process also results in the formation of urea derived byproducts that can influence non-volatile particle number (PN) measurement conducted in accordance with the European Union (EU) Particle Measurement Program (PMP) protocol. In this program, an experimental investigation of the impact of DEF injection on tailpipe PN and its implications for PMP compliant measurements was conducted using a 2015 model year 6.7 L diesel engine equipped with a diesel oxidation catalyst, diesel particulate filter and SCR system. Open access to the engine controller was available to manually override select parameters.

Typical two-site storage-based SCR plant models in literature consider NH3 stored in the first site to participate in NH3 storage, NOx conversion and second site to only participate in NH3 storage passively. This paper focuses on quantifying the impact of stored NH3 in the second site on the overall NOx conversion for an ultra-low NOx system due to intra site NH3 mass transfer. Accounting for this intra site mass transfer leads to better prediction of SCR out NH3 thus ensuring compliance with NH3 coverage targets and improved dosing characteristics of the controller that is critical to achieving ultra-low NOx standard. The stored NH3 in the second site undergoes mass transfer to the first site during temperature ramps encountered in a transient cycle that leads to increased NOx conversion in conditions where the dosing is switched off. The resultant NH3 coverage fraction prediction is critical in dosing control of SCR.

This work is a part of medium-duty Low NOx technology development project with a focus on evaluating a combination of engine and advanced aftertreatment for 0.02 g/bhp-hr NOx regulation proposed by CARB (California air resource board). In this project, a control oriented chemical kinetics model of SCR (Selective catalytic reduction) was used in the aftertreatment controller that is susceptible to performance degradation due to hydrothermal and chemical aging. This paper focuses on modeling the NOx conversion and NH3 storage characteristics using a controls oriented SCR plant model which is further used for a model-based urea dosing scheme. A set of steady state reactor tests were used to calibrate the SCR performance at degreened, hydrothermal only and hydrothermal + chemical aging conditions and also to determine inhibition factors related to aging. The resultant model is capable of simulating SCR performance deterioration such as a reduction in NOx conversion and NH3 storage.

The drive to more fuel efficient vehicles is underway, with passenger car targets of 54.5 mpg fleet average by 2025. Improving engine efficiency means reducing losses such as the heat lost in the exhaust gases. However, reducing exhaust temperature makes it harder for emissions control catalysts to function because they require elevated temperatures to be active. Addressing this conundrum was the focus of the work performed. The primary objective of this work was to identify low temperature limiters for a variety of catalyst aftertreatment types. The ultimate goal is to reduce catalyst light-off temperatures, and the knowledge needed is an understanding of what prevents a catalyst from lighting off, why, and how it may be mitigated. Collectively these are referred to here as low temperature limiters to catalyst activity.

The critical particle size for a high-pressure injection system was determined. Various double-cut test dusts ranging from 0 to 5 μm to 10 to 20 μm were evaluated to determine which test dust caused the high-pressure system to fail. With the exception of the 0- to 5-μm test dust, all test dust ranges caused failure in the high-pressure injection system. Analysis of these evaluations revealed that the critical particle size, in initiating significant abrasive wear, is 6 to 7 μm. Wear curve formulas were generated for each evaluation. A formula was derived that allows the user to determine if the fuel filter effluent will cause harmful damage to the fuel system based on the number of 5-, 10-, and 15-μm particles per milliliter present. A methodology was developed to evaluate fuel filter performance as related to engine operating conditions. The abrasive methodology can evaluate online filter efficiency and associated wear in a high-pressure injection system.

A recently developed in-cylinder fuel injection probe was used to deposit a small amount of liquid fuel on various surfaces within the combustion chamber of a 4-valve engine that was operating predominately on liquefied petroleum gas (LPG). A fast flame ionization detector (FFID) was used to examine the engine-out emissions of unburned and partially-burned hydrocarbons (HCs). Injector shut-off was used to examine the rate of liquid fuel evaporation. The purpose of these experiments was to provide insights into the HC formation mechanism due to in-cylinder wall wetting. The variables investigated were the effects of engine operating conditions, coolant temperature, in-cylinder wetting location, and the amount of liquid wall wetting. The results of the steady state tests show that in-cylinder wall wetting is an important source of HC emissions both at idle and at a part load, cruise-type condition. The effects of wetting location present the same trend for idle and part load conditions.

A number of laboratory-scale test methods are available to predict the effects of fuel lubricity on injection system wear. Anecdotal evidence exists to indicate that these methods produce poor correlation with pump wear, particularly for fuels that contain lubricity additives. The issue is further complicated by variations in the lubricity requirements of full-scale equipment and the test methodologies used to evaluate the pumps. However, the cost of performing full-scale equipment testing severely limits the quantity of data available for validation of the laboratory procedures at any single location. In the present study, the technical literature was reviewed and all previously published data was combined to form a single database of 175 pump stand results. This volume of data allows far more accurate statistical analysis than is possible with tests performed at a single location. The results indicate differences in the effectiveness of the standardized laboratory-scale methods.

A 1991 Toyota Camry equipped with an electrically-heated catalyst (EHC) system was evaluated in duplicate over the Federal Test Procedure (FTP) with three different fuels. Evaluations were conducted with the EHC in place but without any external heating, and with the EHC operated with a post-crank heating strategy. The EHC system was placed immediately upstream of an original production catalyst, which was then moved to a location 40.6 cm from the exhaust manifold. The three test fuels were: 1) the Auto/Oil industry average gasoline, RF-A; 2) a fuel meeting California's Phase II gasoline specifications; and 3) a paraffinic test fuel. Non-methane organic gas (NMOG) emission rates with the EHC active were similiar with all three fuels, with absolute levels less than or equal to California's 50,000 mile Ultra-Low Emission Vehicle (ULEV) standard. Substantial differences, however were observed in the ozone forming potential of these fuels with the EHC active.

A cooperative research and development program was organized to determine the critical particle size of abrasive debris that will cause significant wear in rotary injection fuel pumps. Various double-cut test dusts ranging from 0-5 to 10-20 μm were evaluated to determine which caused the pumps to fail. With the exception of the 0-5-μm test dust, all other test dust ranges evaluated caused failure in the rotary injection pumps. After preliminary testing, it was agreed that the 4-8-μm test dust would be used for further testing. Analysis revealed that the critical particle size causing significant wear is 6-7 μm. This is a smaller abrasive particle size than reported in previously published literature. A rotary injection pump evaluation methodology was developed. During actual operation, the fuel injection process creates a shock wave that propagates back up the fuel line to the fuel filter.

The US Army is currently assessing the feasibility and defining the requirements of a Single Common Powertrain Lubricant (SCPL). This new lubricant would consist of an all-season (arctic to desert), fuel-efficient, multifunctional powertrain fluid with extended drain capabilities. As a developmental starting point, diesel engine testing has been conducted using the current MIL-PRF-46167D arctic engine oil at high temperature conditions representative of desert operation. Testing has been completed using three high density military engines: the General Engine Products 6.5L(T) engine, the Caterpillar C7, and the Detroit Diesel Series 60. Tests were conducted following two standard military testing cycles; the 210 hr Tactical Wheeled Vehicle Cycle, and the 400 hr NATO Hardware Endurance Cycle. Modifications were made to both testing procedures to more closely replicate the operation of the engine in desert-like conditions.